Capillary-assisted bipolar electrochemistry: a focused minireview

L. Bouffier, N. Sojic, A. Kuhn

Electrophoresis, 2017, in press

A bipolar electrode is quite unconventional as it behaves simultaneously as an anode and a cathode in contrast to a classic electrochemical setup where the electron-transfer reactions are promoted on two different electrodes. The driving force is the polarization potential established between the solution and the bipolar electrode which allows a wireless electrochemical addressing. In the past decade or so, bipolar electrochemistry (BPE) has encountered a remarkable renewal of interest with extraordinary potentialities ranging from materials science to analytical chemistry. For practical reasons, BPE experiments are very often performed in home-made electrochemical cells comprising tubes or capillaries. This review is focussed on specific applications based on such types of experimental set-ups, from the macroscale where the tube acts only as an ordinary container down to the microscale where specific properties of the capillary come also into play.

2017-05

Capillary-assisted bipolar electrochemistry: a focused minireview
Monday, 13 March 2017
L. Bouffier, N. Sojic, A. Kuhn Electrophoresis, 2017, in press A bipolar electrode is quite unconventional as it behaves simultaneously as an anode and a cathode in contrast to a classic...
Hierarchical templating in deposition of semi-covalently imprinted inverse opal polythiophene film for femtomolar determination of human serum albumin
Monday, 13 March 2017
M. Dabrowski⁠, M. Cieplak⁠a⁠, P. Sindhu Sharma⁠, P. Borowicz⁠, K. Noworyta⁠, W. Lisowski⁠, F. D'Souza⁠⁠, A. Kuhn⁠, W. Kutner Biosens.&Bioelectron. 2017, 94, 155-161...
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Spatially-resolved multicolor bipolar electrochemiluminescence
Monday, 06 February 2017
Haidong Li, Laurent Bouffier, Stéphane Arbault, Alexander Kuhn, Conor F. Hogan, Neso Sojic Electrochemistry Communications, 2017, in press Here, we describe a new aspect of multicolor...
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Co(III) Complexes of (1,3-Selen-2-yl)hydrazones and Their Sulphur Analogues: Comparative Structural, Electrochemical, Computational and Biological Activity Study
Monday, 06 February 2017
Nenad R. Filipović, Hana Elshaflu, Sonja Grubišić, Ljiljana S. Jovanović, Marko Rodić, Irena Novaković, Aleksandar Malešević, Ivana S. Djordjević, Haidong Li, Nešo Šojić, Aleksandar...
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Efficient Annihilation Electrochemiluminescence of Cationic Helicene Luminophores
Friday, 03 February 2017
Haidong Li, Silvia Voci, Antoine Wallabregue, Catherine Adam, Geraldine M. Labrador, Romain Duwald, Irene Hernández Delgado, Simon Pascal, Johann...
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Applications of Electrogenerated Chemiluminescence in Analytical Chemistry
Wednesday, 18 January 2017
N. Sojic, S. Arbault, L. Bouffier, A. Kuhn Luminescence in Electrochemistry. Applications in Analytical Chemistry, Physics and Biology. Eds. F. Miomandre, P. Audebert, 2017. Springer. The great...
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Recent Advances in Bipolar Electrochemistry
Thursday, 12 January 2017
L. Bouffier, D. Zigah, N. Sojic, A. Kuhn Electroanalytical Chemistry: A Series of Advances, Volume 27, eds. A.J. Bard, C.G. Zoski, 2017, CRC Press, Taylor&Francis Group, in press The concept of...
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Low-Molecular-Weight Hydrogels as New Supramolecular Materials for Bioelectrochemical Interfaces
Thursday, 12 January 2017
D. Jain, A. Karajic, M. Murawska, B. Goudeau, S. Bichon, S. Gounel, N. Mano, A. Kuhn, P. Barthélémy ACS Appl. Mater. Interfaces 2017, in press, DOI: 10.1021/acsami.6b12890 Controlling the...
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Highly Ordered Macroporous Electrodes
Thursday, 12 January 2017
A. Kuhn, M. Heim Springer Handbook of Electrochemical Energy, eds. C. Breitkopf, K. Swider-Lyons, Chapter 6 p143-206, Springer Verlag, Berlin 2017, ISBN:978-3-662-46656-8 In this book chapter, we...
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Full-Spectral Multiplexing of Bioluminescence Resonance Energy Transfer in Three TRPV Channels
Thursday, 12 January 2017
H. J. Ruigrok, G. Shahid, B. Goudeau, F. Poulletier de Gannes,E. Poque-Haro, A. Hurtier, I. Lagroye, P. Vacher, S. Arbault, N. Sojic, B. Veyret, Y. Percherancier Biophysical Journal, 2017, 112,...
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Bright Electrochemiluminescence Tunable in the Near-Infrared of Chiral Cationic Helicene Chromophores
Wednesday, 11 January 2017
Haidong Li, Antoine Wallabregue, Catherine Adam, Geraldine M. Labrador, Johann Bosson, Laurent Bouffier, Jérôme Lacour, Neso Sojic J. Phys. Chem. C,...
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