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dimanche 30 avril 2017

Site-Selective Synthesis of Janus-type Metal-Organic Framework Composites

Yadnum S., Roche J., Lebraud E., Négrier P., Garrigue P., Bradshaw D., Warakulwit C., Limtrakul J., Kuhn A.
Angew. Chem. Int. Ed. 2014, 126, 4082-4086.

Herein, bipolar electrochemistry is applied in a straightforward way to the site-selective in situ synthesis of metal–organic framework (MOF) structures, which have attracted tremendous interest in recent years because of their significant application potential, ranging from sensing to gas storage and catalysis. The novelty of the presented work is that the deposit can be intentionally confined to a defined area of a substrate without using masks or templates. The intrinsic site selectivity of bipolar electrochemistry makes it a method of choice to generate, in a highly controlled way, hybrid particles that may have different functionalities combined on the same particle. The wireless nature of electrodeposition allows the potential for mass production of such Janus-type objects.



Propulsion of microobjects by dynamic bipolar self-regeneration
J. Am. Chem. Soc. 2010132, 15918-15919.

Multiresponsive hybrid microgels and hollow capsules with a layered structure
Langmuir 200925, 4659-4667.

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